河南中牟区块页岩气特征及勘探前景分析          下载免费PDF全文

邱庆伦  张古彬  冯辉  张栋  张馨元 《地质找矿论丛》2018,33(1):70-75

文章通过对河南中牟区块海陆过渡相太原组和山西组页岩气形成的地质条件与特征分析,认为区块构造较为简单、稳定,其海陆交互相沉积环境控制太原组和山西组页岩发育,分布广泛,富含有机质页岩厚度大,为页岩气目标层;有机碳含量w(TOC)=1.1%~3.7%,有机质类型为Ⅲ型,有机质成熟度指标镜质体反射率(Ro)3.0%~3.8%;目标层有效孔隙度1.0%~5.0%,黏土矿物以伊利石和伊/蒙混层为主;含气量0.5~3.3m~3/t,平均1.7m~3/t。对牟页1井太原组、山西组三段采用快钻桥塞分段压裂,累计注入压裂液量5 055.9m~3,加砂量202.7m~3,三层合采求产为1 256m~3/d,标志着南华北盆地海陆过渡相页岩气勘探取得重大发现。通过地质评价和资源量计算,中牟区块太原组、山西组页岩气地质资源量较为丰富,勘探有利区面积大,具备较好的页岩气勘探前景。  相似文献   

新疆四顶黑山花岗岩体锆石LA-ICP-MS U-Pb年龄及地质意义          下载免费PDF全文

王静  王学武  邓明国  孙涛 《地质找矿论丛》2018,33(3):365-374

新疆东天山位于中亚造山带南缘,天山—兴安造山系北天山造山带东段,发育大量泥盆纪—石炭纪花岗岩,其形成过程多与觉罗塔格洋的俯冲作用有关。四顶黑山花岗岩体位于东天山觉罗塔格构造岩浆带的东端,岩体在地表呈不规则状产出,侵位于元古界片岩-变火山岩、奥陶系变玄武岩和泥盆系雀儿山群火山岩;主要岩石类型为花岗岩和花岗闪长岩。花岗岩的LA-ICP-MS锆石U-Pb年龄为380.4 Ma±3.7 Ma,表明岩体形成于晚泥盆世。岩石表现出高硅(w(SiO_2)=64.87%~74.71%)、高碱(w(K_2O)=3.35%~4.68%,w(Na_2O)=2.26%~3.85%)、富铝(w(Al_2O_3)=11.82%~14.13%)和低MgO(w(MgO)=0.56%~2.12%)、CaO(w(CaO)=1.68%~3.74%)、TiO_2(w(TiO_2)=0.26%~0.57%)、P_2O_5(w(P_2O5)=0.01%~0.19%)特征,A/CNK=0.83~1.00;富集Ba、K、La、Ce、Nd,亏损Th、Nb、Ta、Sr、Ti,铕负异常较明显(δEu=0.70~0.73);具有岛弧型花岗岩特征。四顶黑山花岗岩体形成于岛弧环境,属于觉罗塔格洋向南俯冲过程中的产物。四顶黑山花岗岩体两侧的镁铁-超镁铁质岩体的形成时代应晚于晚泥盆世。  相似文献   

东昆仑祁漫塔格地区晚三叠世正长花岗岩岩石成因及构造意义     

张明玉  丰成友  王辉  李大新  瞿泓滢  刘建楠  周建厚 《岩石矿物学杂志》2018,37(2):197-210

青海省东昆仑祁漫塔格地区肯德可克矿区外围东部发育一正长花岗岩体,主要矿物组合为正长石(50%~60%)+石英(20%~30%)+斜长石(10%~20%)+黑云母(1%~5%)。其LA-ICP-MS锆石U-Pb加权平均年龄为217.9±1.7 Ma(MSWD=0.74,n=20),形成时代为晚三叠世,与祁漫塔格地区铁多金属矿床基本同时形成。岩石地球化学组成具有高硅(Si O2=74.53%~75.28%)、富碱(K2O+Na2O=8.81%~8.95%)、富铁贫镁(Fe OT/Mg O=18.02~31.48)的特征,并具强烈的负Eu异常(δEu=0.04~0.05),富集Rb、Th、U、K、Ga,亏损Sr、Ba、Ta、P、Ti,显示其为准铝质A型花岗岩。正长花岗岩锆石εHf(t)为2.0~12.4,平均6.4,显示其源区具有壳幔混合作用的特征,壳幔物质交换为区内铁多金属矿化提供了大量成矿物质。该正长花岗岩属A2型花岗岩,暗示其形成于造山后的伸展构造体制,反映了祁漫塔格地区晚华力西-印支期造山旋回于晚三叠世由造山后期转为伸展阶段。  相似文献   

The Late Triassic I–Type Granites from the Longmu Co–Shuanghu Suture Zone in the interior of Tibetan Plateau, China: Petrogenesis and Implication for Slab Break–Off     

ZHAO Zhen  WU Zhenhan  LU Lu  YU Junqiu  WU Yanjun 《《地质学报》英文版》2018,92(3):935-951

The Jiangaidarina granitic mass(JM) is an important part of the magmatic belt in Longmu CoShuanghu Suture Zone(LSSZ) in the central Tibetan Plateau. An integrated research involving wholerock geochemistry, zircon LA-ICP-MS U-Pb ages and Hf isotopic compositions was carried out to define the timing, genesis and tectonic setting of the JM. Zircon LA-ICP-MS U-Pb ages have been obtained ranging from 210 to 215 Ma, rather than the Early Jurassic as previously thought. Fifteen granite samples contain hornblendes and show a negative correlation between P_2 O_5 and SiO_2, indicating that the JM is an I-type granite. All the granites are enriched in LREE relative to HREE, with negative Eu anomalies(Eu/Eu*=0.56-0.81), and have similar trace elements patterns, with depletion of Ba, Nb, Sr and P. These suggest that the JM was fractionated, and this is also proved by the characteristic of negative correlations between oxide elements(TiO_2, MgO, FeOt, MnO, CaO) and SiO_2. Almost all ε_(Hf)(t) values of the granites are between-10.3 and-5.8, implying that the JM has a crustal source intimately related with the South Qiangtang Block(SQB), except for one(+10.2), showing a minor contribution from mantle source.Moreover, relatively low Na_2 O/K_2 O ratios(0.42-0.93) and high A/CNK values(0.91-1.50) reflect that the JM was predominately derived from the medium-high potassium basaltic crust, interacted with greywacke. Our new geochemical data and geochronological results imply that the Late Triassic magmas were generated in a post-collisional tectonic setting, probably caused by slab break-off of the Longmu Co-Shuanghu Tethyan Ocean(LSTO). This mechanism caused the asthenosphere upwelling, formed extension setting, offered an enormous amount of heat, and provided favorable conditions for emplacement of voluminous felsic magmas. Furthermore, the LSTO could be completely closed during the Middle Triassic, succeed by continental collision and later the slab broke off in the Late Triassic.  相似文献   

北淮阳东段西汤池岩体地球化学特征、锆石U-Pb定年及成因     

杨义忠  王徽  蔡杨 《江苏地质》2018,42(2):187-196

西汤池岩体位于安徽北淮阳地区舒城县西汤池一带。西汤池似斑状二长花岗岩具高硅、富碱质特征,为铝饱和碱性系列岩石。稀土元素含量中等,(La/Yb)_N与HREE/LREE值较高,重稀土相对轻稀土亏损明显,Eu呈弱负异常,属轻稀土富集型。大离子亲石元素(Rb、K、La、Nd等)明显富集,而高场强元素(Nb、Ta、P、Ti等)亏损。通过LA-ICP-MS锆石U-Pb定年,获得西汤池二长花岗岩~(206)Pb/~(238)U年龄为(125.5±1.6)Ma,为早白垩世岩浆活动的产物。基于前人关于北淮阳地区区域地质背景方面的研究成果和本次地球化学构造环境判别方面的研究,认为西汤池二长花岗岩属A_1型花岗岩,形成于后碰撞的伸展构造环境。  相似文献   

广东良口黄田埔高分异Ⅰ型花岗岩地球化学特征及大地构造意义     

苏扣林 《江苏地质》2018,42(2):197-205

广州从化区良口亚髻山霞石正长岩为典型岩石遗迹,在碱性岩体野外填图研究过程中,新发现东侧分布有黄田埔高分异花岗岩,形成时间约(146±13)Ma,为晚侏罗世岩浆活动产物。元素地球化学特征显示硅高、钾富、分异指数高、Rb/Sr比值高以及Rb/Ba、Nb/Ta、Zr/Hf、TFeO/MgO比值低;稀土元素ΣREE平均值为248 g/t,ΣCe/ΣYb平均值为2.34,δEu(0.16)负异常明显;Ga(×10~4)/Al比值较低(平均值为3.47),Zr+Nb+Ce+Y含量(平均值为264g/t)低于A型花岗岩(350 g/t);I(Sr)值为0.691 8~0.712 8,平均值为0.708 1;ε_(Nd)(t)值为-3.5~-10.0,平均值为-6.7。元素地球化学、同位素地球化学和同位素年代学综合研究结果表明,岩株的形成可能与上地幔岩浆分异有关,为高分异Ⅰ型花岗岩。  相似文献   

内蒙古阿拉善右旗大山口地区黑云母花岗岩地球化学特征及成因          下载免费PDF全文

李伟  赵飞  熊文勃  李延涛  黄瀚清 《甘肃地质》2018,(2):29-35

内蒙古自治区阿拉善右旗大山口地区发育有大面积侵入岩,主要为华力西中晚期和印支期酸性侵入岩体及各类脉岩。本次运用LA-ICP-MS锆石U-Pb测年方法获得黑云母花岗岩的成岩年龄为229.5±5.6 Ma,属晚三叠世,大山口黑云母花岗岩SiO_2含量68.89%～71.04%,相对富钾贫钠;A/NKC介于0.89～1.05,强烈富集强不相容元素,亏损高场强元素Na、Ta、Ti、P,Eu异常不明显,HREE呈近平坦型分布。通过黑云母花岗岩的成因研究和构造环境判别分析,认为大山口黑云母花岗岩为加厚的中下地壳物质拆沉进入地幔加热并发生部分熔融,且熔体可能与地幔基性熔体发生一定程度的混合作用后上升形成的花岗岩,形成于晚三叠世后碰撞伸展垮塌的构造环境。  相似文献   

花岗岩定量分类方法及与成矿空间相关关系分析 ——甘肃省西秦岭地区为例          下载免费PDF全文

王晓伟  罗建民  王玉玺  张琪  宋秉田  杨忠明  赵彦庆 《甘肃地质》2018,(1):26-31

以Q型系统聚类分析(以组内连接为聚类方法,相关性为计算模型)和判别分析交替使用的方法,对甘肃省西秦岭地区花岗岩样本中的11个氧化物测试数据进行定量处理,构建起"甘肃省西秦岭地区花岗岩(氧化物)定量分类系列模型",将西秦岭地区花岗岩分为3大类共8小类。分类结果偏重于找矿分类,依据其与西秦岭地区铜矿、铅锌矿、金矿等依据空间关系(距离岩体3 km以内),寻找"成矿相关岩体",确定找矿靶区。  相似文献   

张广才岭南段两个侏罗纪花岗岩体的地球化学特征及其地质意义     

句高  梁一鸿  孙晓  周静 《世界地质》2018,37(2):374-384

通过LA-ICP-MS锆石U-Pb定年和岩石化学分析,研究了张广才岭南段上营北岩体和帽儿山岩体的形成年代,地球化学特征和形成环境。上营北岩体为中粗粒钾长花岗岩,帽儿山岩体为中细粒黑云母钾长花岗岩。上营北岩体的加权平均年龄为178.9±2.7 Ma,帽儿山岩体为183.7±2.4 Ma,均为早侏罗世侵入岩。上营北岩体和帽儿山岩体主量元素都具有Si O_2和K_2O含量较高,Ti O_2、Mg O、Ca O含量较低,TFe O/Mg O值较高的特点;上营北岩体A/CNK=0.98~1.08,里特曼指数σ=1.51~2.66;帽儿山岩体含铝指数A/CNK=1.00~1.01,里特曼指数σ=2.12~2.36。上营北岩体稀土元素配分模式为海鸥型,轻重稀土分馏不明显;帽儿山岩体稀土元素配分模式为右倾型,轻稀土较重稀土富集;两个岩体均富集Rb、K,Ba、Nb、Ta、Sr、Ti、P、Ho、Er、U、Eu等元素出现不同程度的亏损。地球化学特征分析显示上营北岩体和帽儿山岩体均为A_2型花岗岩,为后造山型花岗岩,形成于兴蒙造山带后造山的伸展环境。  相似文献   

Geochemistry of organic matter and elements of black shale during weathering in Northern Guizhou,Southwestern China: Their mobilization and inter-connection     

Xuan Tang  Jinchuan Zhang  Yang Liu  Chao Yang  Qian Chen  Wei Dang  Panwang Zhao 《Chemie der Erde / Geochemistry》2018,78(1):140-151

Different from previous studies on effect of weathering upon geochemical variation along a single weathered profile, this paper provides a new methodology validated by comparing a weathered outcrop samples and their stratigraphic counterpart un-weathered core samples in a nearby shallow borehole. This outcrop and borehole penetrated the Ordovician-Silurian Wufeng–Longmaxi shales, located in the same anticline structure in the northern part of Guizhou Province, Southern China. The mineral composition, major, trace and rare earth elements (REEs) composition and Rock-Eval parameters of outcrop and core samples were analyzed and compared. Organic matter (OM) was observed in the microscope and extracted for elements analysis. The results show that short-term weathering still has significant influence on OM, mineral and elemental composition of black shales. The elements composition shows the outcrop profile was moderately weathered. The REEs compositions do not alter much during weathering process and the REEs composition and their relative ratios still are valid for rock origin determination. The OM, mainly composed by graptolite and bitumen, even entering the highly-over thermal maturity, is still sensitive to the weathering with a systematic loss 30–50% of TOC along the outcrop profile, which suggests that the OM consumption is predominantly controlled by weathering duration and the distance from the weathering surface. In turn, OM has significant influence on the trace elements transportation behavior during weathering. Some trace elements associated with the OM such as V, Cr, Th, U, Ni and Co, change significantly in their absolute concentration during weathering, but their relative ratios do not necessarily change too much and might be still reliable proxies for paleo-environmental determination. The mobility of shale minerals during weathering is in the following order: plagioclase?>?potassium feldspar and dolomite >pyrite and OM. Short-term weathering can also result in considerable transportation of elements and significant variation of minerals content in black shale, which may pose potentially high environmental and engineering risk in the regions rich in black shale.  相似文献